We have developed a straightforward method for creating large-area, microscale resolution patterns of functional amines on self-assembled monolayers. The technique utilizes flat elastomeric stamp enriched with photoacid and HD-DVD optical pickup to locally deprotect the N-Boc groups and form chemical patterns with resolution below 10µm. Further details can be found in the article published in ACS Applied Materials and Interfaces: https://pubs.acs.org/doi/10.1021/acsami.2c20568 .